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Akashi, Masatsune*; Fukaya, Yuichi*; Asano, Hidekazu*
JNC TJ8400 2000-014, 22 Pages, 2000/02
JNC-TJ8400-2000-014.pdf:0.75MB
Difference of hydrogen generation phenomena on the surface of the Steels were not observed between carbon steel, atmospheric corrosion resisting steel and 5%-Ni steel. Rust layer was formed on these three-type of steels by steam oxidation method. And the chemical composition of the rust for the steels were basically two(2) layers structure for the previous two steels as hematite(Fe
O
) based for the outer layer and magnetite(FeO
) based for the inner layer. And for the last steel, it had three(3) layer in the rust as hematite(FeO) based for the outer layer, magnetite(FeO) based for the intermediate layer and Ni based layer for the inner layer. These steels showed mostly same Tafel gradient in their cathodic polarization curves compare with that for no rust specimens. However, the exchange current density which reaction is assumed as a hydrogen generation reaction was largely increased. The cathodic reaction for each steels whose surface is covered by magnetite layer might be accelerated, then the corrosion rate was considered as accelerated, too.
*
PNC TJ9605 91-001, 28 Pages, 1990/10
The present report describes the results of studies performed sa a part of the results of "CORROSION TESTS OF CLADDING INNER SURFACE COATING" during a period of Feb. 20 - Mar.30, 1990. In the present study, corrosion tests have been carried out with CsOH to evaluate corrosion resistance of ferritic stainless steel and coated stainless steel. The following results were drawn from the present study (1)Corrosion tests of austenitic and ferritic stainless steel with ScOH were made at temperatures of 500-700
C. After corrosin tests, intergranular attack was found to occur in the austenitic steel, however, there was no intergranular attack in the ferritic steel. Ferritic steel appears to have corrosion resistance to liquid CsOH superior to austenitic steel. (2)Corrosion tests between Ni-Ti, Ti, Al coatings on stainless steel and CsOH were made at temperature of 500-700C. Ni-Ti and Al coated stainless steel showed no intergranular attack, though the coatings were locally detached from the stainless stell substrates. Intergranular attack was observed in the Ti coated stainless steel. Ni-Ti and Al coating seem to be useful for reduction of intergranular attack of stainless steel cladding.
; Kondo, Tatsuo
Tetsu To Hagane, 70(1), p.112 - 119, 1984/00
no abstracts in English
